Current LLMs are generally aligned to follow safety requirements and tend to refuse toxic prompts. However, LLMs can fail to refuse toxic prompts or be overcautious and refuse benign examples. In addition, state-of-the-art toxicity detectors have low TPRs at low FPR, incurring high costs in real-world applications where toxic examples are rare. In this paper, we explore Moderation Using LLM Introspection (MULI), which detects toxic prompts using the information extracted directly from LLMs themselves. We found significant gaps between benign and toxic prompts in the distribution of alternative refusal responses and in the distribution of the first response token's logits. These gaps can be used to detect toxicities: We show that a toy model based on the logits of specific starting tokens gets reliable performance, while requiring no training or additional computational cost. We build a more robust detector using a sparse logistic regression model on the first response token logits, which greatly exceeds SOTA detectors under multiple metrics.